At the beginning of June, the low-odor polyether products produced by Gaoqiao Petrochemical started to supply to customers, marking the success of the two-year research to reduce the content and odor of polyether aldehydes.
In October 2011, General Administration of Quality Supervision, Inspection and Quarantine (AQSIQ) and Ministry of Environmental Protection (MEP) issued the national standard “Guidelines for the Evaluation of Air Quality in Passenger Cars”, which specifies the content of harmful volatile substances in passenger cars. Highly reactive polyether polyols and polymer polyols produced by Takahashi Petrochemical are the main bulk raw materials for its core customers to produce seat foam bodies, which contain formaldehyde, acetaldehyde, acrolein and styrene as the main sources of aldehydes in vehicles. To this end, the customer proposed specific improvement targets and asked Takahashi Petrochemical to address them as quickly as possible.
After reviewing a lot of information in English and Chinese, and combining the research work conducted in the laboratory and relevant production experience, Takahashi Petrochemical researchers found that in the polyether synthesis process, the side reactions would increase the content and odor of small molecules of ketone aldehydes in polyether, while the storage temperature and storage conditions of polyether also have a great impact on the aldehyde content.
In December 2011, Gaoqiao Petrochemical set up a research group to reduce the content of aldehydes (focusing on acetaldehyde) in polyether. In the production of polyether, the acetaldehyde content was reduced from 40ppm to less than 10ppm by controlling the reaction and refining process; and the acetaldehyde content was further reduced to less than 5ppm by post-processing the finished single kettle polyether with de-formaldehyde. Tested by a third-party testing organization, its test results matched with Takahashi Petrochemical.
In February 2013, Takahashi Petrochemical established an accurate test method for polyether aldehyde and ketone content, completed the work of aldehyde reduction under the existing formulation system and cured it into the operation instruction, and each batch of high activity polyether also reached the improvement target of formaldehyde ≤ 3ppm, acetaldehyde ≤ 5ppm and acrolein ≤ 5ppm proposed by the customer, and made this as the factory index of polyether products.
In the middle of March 2013, based on the results achieved in the first stage of the attack, the attack team put the heavy shut.The customer’s evaluation result is that the odor of polyether and foam is much lower after the improvement, which is basically the same as foreign products; the aldehyde content of polyether is greatly reduced; the other physical properties of the foam issued by polyether are basically the same as before the improvement.
According to the customer’s requirement that polyether does not contain phenol, from January to April 2014, Gaoqiao Petrochemical conducted a large number of antioxidant screening, looking for both making polyether phenol-free and inhibiting the production of polyether aldehyde content, after several industrial trial production, we found the antioxidant that meets the requirements.
In the middle of May, the customer applied GEP-828, a low odor polyether, for foaming industrial trial production, and achieved satisfactory results. early June, Gaoqiao Petrochemical started to sell GEP-828, a low odor polyether, for customer use.